Buckyballs gain smaller kin

June 2/9, 2004

Researchers from Xiamen University and the Chinese Academy of Sciences have constructed a smaller version of the buckyball or C60 fullerene molecule, a spherical cage of carbon atoms.

The researchers were able to synthesize relatively large quantities of the smaller fullerene molecules by mixing carbon tetrachloride and graphite to get C50 molecules. Fullerenes smaller than C60 are predicted to have unusual electronic and magnetic properties because they're highly curved, with a shape between a sphere and a disk.

Buckyballs are made from carbon atoms arranged in exactly 12 pentagons and some number of hexagons, which isolate the pentagons from each other, allowing molecules to form as spheres. The smaller fullerene molecules don't satisfy the isolated pentagon rule, but instead contain pentagons abutting around the periphery of the molecule.

The key to producing the smaller buckyballs was causing chlorine atoms to attach to the carbon atoms that are shared by abutting pentagons. The chlorine atoms form a ring around and stabilize the molecular structure.

The new structures, like buckyballs, are related to carbon nanotubes, which are rolled-up sheets of carbon atoms that have useful electrical, optical and mechanical properties and show promise in nanotechnology.

The method can also be used to make other smaller fullerenes, according to the researchers.

It's not yet clear what the new material might be used for, according to the researchers. The work appeared in the April 30, 2004 issue of Science.

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